Editorial Technical Reference

pH Electrode

This page explains how pH Electrode is classified within Chemical Manufacturing. Technical values and manufacturer relationships are research references; confirm the current specification and supplier evidence for each order.

Technical Definition & Core Assembly

Electrochemical sensor component that measures hydrogen ion concentration in aqueous solutions by generating a voltage proportional to pH.

Representative product image. Confirm appearance and specifications with the manufacturer.

Product Specifications

Technical details and manufacturing context for pH Electrode

Definition
The pH Electrode is a component used in chemical manufacturing to measure the acidity or alkalinity of aqueous solutions. It is a critical sensing element within pH/Conductivity Sensor systems, detecting hydrogen ion activity through a pH-sensitive glass membrane. The electrode converts chemical information into electrical signals, enabling pH measurement and monitoring. It operates based on the Nernst equation, where the glass membrane develops a potential difference proportional to hydrogen ion concentration when immersed in solution, with a reference electrode providing a stable potential for comparison. The electrode is constructed with pH-sensitive glass, silver/silver chloride, potassium chloride electrolyte, and an epoxy body. It measures a pH range of 0–14, with an accuracy of ±0.01 pH at 25°C within calibration buffer. Response time is ≤30 seconds to reach 95% of the final value. Operating temperature is 0–80°C for continuous operation, with higher temperatures allowed for short periods. Storage temperature is -10–60°C, and the electrode must be kept moist. Maximum pressure is 0.6 MPa at 25°C; higher pressure may damage the membrane. Zero point is 7.00 ±0.10 pH at 25°C in pH 7 buffer. Slope is 95–102% relative to theoretical Nernstian slope. Internal resistance is ≤250 MΩ at 25°C, increasing with age. Cable length options are 1–5 meters, with BNC connector type standard; other connectors available on request. Body and membrane materials are Glass/PVDF. Weight ranges from 100–200 g depending on cable length and connector. These specifications are directory reference ranges; verify model-specific values with the legal manufacturer or supplier before procurement.
Working Principle
The pH Electrode operates based on the Nernst equation. A pH-sensitive glass membrane develops a potential difference proportional to the hydrogen ion concentration when immersed in an aqueous solution. This potential is measured against a stable reference electrode (silver/silver chloride) immersed in a potassium chloride electrolyte. The voltage difference is converted into a pH reading. The glass membrane selectively responds to hydrogen ions, and the reference electrode provides a constant potential, allowing accurate measurement across the 0–14 pH range.
Common Materials
pH-sensitive glass, Silver/silver chloride, Potassium chloride electrolyte, Epoxy body
Technical Parameters
ParameterTypical rangeNotes & selection driver
Measurement Range0–14 pHFull pH range for aqueous solutions
Accuracy±0.01 pHAt 25°C, within calibration buffer
Response Time≤30 sTo reach 95% of final value
Operating Temperature0–80 °CContinuous operation; higher for short periods
Storage Temperature-10–60 °CKeep electrode moist
Maximum Pressure0.6 MPaAt 25°C; higher pressure may damage membrane
Zero Point7.00 ±0.10 pHAt 25°C in pH 7 buffer
Slope95–102 %Relative to theoretical Nernstian slope
Internal Resistance≤250 At 25°C; increases with age
Cable Length1–5 mStandard options; custom lengths available
Connector TypeBNCOther connectors on request
MaterialGlass/PVDFBody and membrane materials
Weight100–200 gDepending on cable length and connector

Ranges are indicative industry figures for RFQ preparation, not a supplier commitment. Confirm every value and standard with the legal manufacturer before ordering.

Components / BOM
  • Glass membrane Part
    pH-sensitive element that selectively responds to hydrogen ions
    Material: pH-sensitive glass
  • Reference electrode
    Provides stable reference potential for measurement
    Material: Silver/silver chloride
  • Electrolyte solution Part
    Maintains ionic contact between reference electrode and sample
    Material: Potassium chloride gel
  • Electrode body Part
    Protects internal components and provides structural integrity
    Material: Epoxy or glass

Applied To / Applications

This component is essential for the following industrial systems and equipment:

Industrial Ecosystem & Supply Chain Structure

Complementary Systems
Downstream Applications
Specialized Tooling

Application Fit & Sizing Matrix

Operational Limits
pressure: 0-6 bar (0-87 psi) standard, high-pressure models up to 16 bar (232 psi)
flow rate: 0-3 m/s (0-10 ft/s) recommended to prevent abrasion
temperature: 0-80°C (32-176°F) typical, some models up to 100°C (212°F)
slurry concentration: ≤10% solids by weight for standard electrodes, specialized models for higher concentrations
Media Compatibility
✓ Potable water treatment ✓ Chemical process solutions (acids/bases) ✓ Food and beverage production
Unsuitable: Hydrofluoric acid solutions (attacks glass membrane)
Sizing Data Required
  • Process temperature range
  • pH measurement range required
  • Chemical composition of process media

Reliability & Engineering Risk Analysis

Failure Mode & Root Cause
Reference Junction Contamination
Cause: Process fluid ingress or fouling of the reference electrode, causing drift and inaccurate pH readings due to compromised electrolyte diffusion.
Glass Membrane Degradation
Cause: Chemical attack from high-alkaline solutions (pH >12) or hydrofluoric acid, leading to etching, increased impedance, and slow response times.
Maintenance Indicators
  • Drifting or unstable pH readings despite calibration
  • Visible cracks, cloudiness, or deposits on the glass bulb
Engineering Tips
  • Implement routine cleaning with appropriate solutions (e.g., pepsin-HCl for proteins, dilute HCl for general deposits) and store in KCl storage solution when not in use.
  • Use protective sleeves or flow chambers in abrasive or high-temperature applications, and select specialized glass (e.g., low-resistance, high-temperature) for harsh chemical environments.

Indicative industry ranges for design and RFQ preparation. Confirm the exact figures and applicable standard with the manufacturer before specifying.

Compliance & Manufacturing Standards

Applicable Standards
ISO 17025:2017 - General requirements for the competence of testing and calibration laboratories ASTM E70 - Standard Test Method for pH of Aqueous Solutions with the Glass Electrode CE marking - Compliance with EU directives for electromagnetic compatibility and safety

Quoted from the published standard.

Manufacturing Precision
  • pH accuracy: +/-0.02 pH units
  • Response time: 95% within 30 seconds
Quality Inspection
  • Calibration verification against NIST-traceable buffer solutions
  • Electrode slope and offset measurement per ASTM E70

Manufacturers of pH Electrode

1 company lists this product among what they make. Company figures are quoted from each company's own website; every card states where the relationship came from.

Shanghai BOQU Instrument Co., Ltd.
Shanghai, CN
Listed on the company's own website · profile compiled by CNFX from public sources

Manufacturer listings support early research and capability understanding. They are not certification, ranking, or transaction guarantees.

Technical documentation
Request current drawings, revision history, and a signed specification sheet.
Manufacturing capability
Verify equipment lists, process limits, capacity, and representative production evidence.
Inspection readiness
Confirm test methods, calibrated equipment, sampling plans, and traceable reports.
Supplier transparency
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Frequently Asked Questions

What is the measurement range of this pH electrode?

The directory lists a measurement range of 0–14 pH for aqueous solutions. However, actual performance may vary by model and application, so verify with the manufacturer.

What is the operating temperature range?

The listed operating temperature is 0–80°C for continuous operation, with higher temperatures allowed for short periods. Storage temperature is -10–60°C, and the electrode must be kept moist.

What is the maximum pressure the electrode can withstand?

The maximum pressure is 0.6 MPa at 25°C. Higher pressure may damage the membrane, so ensure the application does not exceed this limit.

What connector types are available?

The standard connector type is BNC, but other connectors are available on request. Cable lengths range from 1 to 5 meters, with custom lengths possible.

Data Basis

Editorial classification, named public sources where available, and source-reviewed manufacturer records.

Preliminary Technical Classification
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